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undergraduate thesis
Organometalni spojevi metala d-bloka
2020. urn:nbn:hr:182:400624
Zajkić, Hana
Josip Juraj Strossmayer University of Osijek
Department of Chemistry

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Zajkić, H. (2020). Organometalni spojevi metala d-bloka (Undergraduate thesis). Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:400624

Zajkić, Hana. "Organometalni spojevi metala d-bloka." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2020. https://urn.nsk.hr/urn:nbn:hr:182:400624

Zajkić, Hana. "Organometalni spojevi metala d-bloka." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2020. https://urn.nsk.hr/urn:nbn:hr:182:400624

Zajkić, H. (2020). 'Organometalni spojevi metala d-bloka', Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 18 April 2024, https://urn.nsk.hr/urn:nbn:hr:182:400624

Zajkić H. Organometalni spojevi metala d-bloka [Undergraduate thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2020 [cited 2024 April 18] Available at: https://urn.nsk.hr/urn:nbn:hr:182:400624

H. Zajkić, "Organometalni spojevi metala d-bloka", Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:182:400624

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Metadata
TitleOrganometalni spojevi metala d-bloka
Title (english)Organometallic compounds of d-block elements
AuthorHana Zajkić
MentorTomislav Balić (mentor)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
Osijek
Defense date and country2020-09-24, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Organski spojevi koji posjeduju minimalno jednu kovalentnu vezu između atoma ugljika i atoma metala klasificiraju se kao organometalni spojevi. Metal u metalnim karbonilima istog koordinacijskog broja poput oksidacijskog stanja podliježe 18 – elektronskom pravilu. U slučaju istih orbitalnih karekteristika dva fragmenta klastera definiraju se kao izolobalna. Primjena izolobalnog odnosa uzmeđu klastera na Wade-ovo pravilo omogućava njegovu primjenu pri brojanju elektrona jednostavnih organometalnih spojeva. Mingosovo pravilo nalazi primjenu pri brojanju ukupnog broja valentnih elektrona polinuklearnih organometalnih spojeva u slučaju kada se Wade-ovim pravilom isti ne mogu strukturno opisati. Najvažnije organometalne reakcije su β-hidrogen eliminacija, α-hidrogen apstrakcija, supstitucija CO ligand, migracija vodika i alkila te oksidativna adicija.
Abstract (english)
Organic compounds that have at least one covalent bond between carbon atoms and metal atoms are classified as organometallic compounds. Metal in metal carbonyls of the same coordination number as oxidation state is subject to an 18- electron rule. In the case od the same orbital characteristics, 2 cluster fragments are defined as isolobal. The application of the isolobal relationship between clusters to the Wade rule allows it to be applied in the case of counting electrons of simple organometallic compounds. The Mingos rule finds application in counting the total number of valent electrons of polynuclear organometallic compounds when the Wade rule can not structurally describe them. The most important organometall reactions are: β-hydrogen elimination, α-hydrogen abstraction, CO ligand substitution, hydrogen and alkyl migration and oxidative addition.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:400624
Study programmeTitle: Chemistry
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2020-12-14 13:14:45