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undergraduate thesis
Krunski eteri, kriptandi i sferandi
2019. urn:nbn:hr:182:303307
Jurišić, Mirjana
Josip Juraj Strossmayer University of Osijek
Department of Chemistry
Department of General, Inorganic and Physical Chemistry and Methodology of Chemistry

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Jurišić, M. (2019). Krunski eteri, kriptandi i sferandi (Undergraduate thesis). Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:303307

Jurišić, Mirjana. "Krunski eteri, kriptandi i sferandi." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2019. https://urn.nsk.hr/urn:nbn:hr:182:303307

Jurišić, Mirjana. "Krunski eteri, kriptandi i sferandi." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2019. https://urn.nsk.hr/urn:nbn:hr:182:303307

Jurišić, M. (2019). 'Krunski eteri, kriptandi i sferandi', Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 19 November 2024, https://urn.nsk.hr/urn:nbn:hr:182:303307

Jurišić M. Krunski eteri, kriptandi i sferandi [Undergraduate thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2019 [cited 2024 November 19] Available at: https://urn.nsk.hr/urn:nbn:hr:182:303307

M. Jurišić, "Krunski eteri, kriptandi i sferandi", Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:182:303307

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Metadata
TitleKrunski eteri, kriptandi i sferandi
Title (english)Crown ethers, criptands and spherands
AuthorMirjana Jurišić
MentorTomislav Balić (mentor)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
(Department of General, Inorganic and Physical Chemistry and Methodology of Chemistry)
Osijek
Defense date and country2019, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Inorganic Chemistry
Abstract
Krunski eteri spadaju u skupinu spojeva koji se zovu makrociklički spojevi. Karakterizira ih prstenasta struktura koja se sastoji od niza eterskih jedinica između kojih se mogu nalaziti i heteroatomi poput dušika, sumpora, itd. Najviše su proučavani zbog sposobnosti stvaranja kompleksnih spojeva s raznim ionima metala. U takvom kompleksnom spoju ion metala je „gost“ a krunski eter je „domaćin“. Krunski eter određene veličine prstena favorizira kompleksiranje određenog iona metala. Ta pojava se naziva „templatnim efektom“ te zahvaljujući njemu je moguće unaprijed odrediti strukturu kompleksnog spoja koja će savršeno odgovarati veličini metalnog iona. Primjer takvog domaćina su sferandi, koji su visokoselektivni prema ionima kalija te se zbog toga koriste u određivanju koncentracije kalija u krvi bolesnika. Budući da mogu kompleksirati i anione metala- alkalide, kriptandi su primjenu našli u ionskoj kromatografiji i anionskoj polimerizaciji.
Abstract (english)
Crown ethers are a class of compounds that are called macrocycles. They have ring structure that consists of ether units which can alternate with heteroatoms such as nitrogen, sulphur, etc. The most studied property of crown ethers is their ability to complex various ions. In such compound metal ion is guest and crown ether is host. Crown ether of different ring size favor complexation with different metal ion. This concept is called „template effect“ so one can design crown structure that will perfectly fit with metal ion. Example of this type of host are spherands that are highly selective toward potassium ions so they are turned into sensors for detection of K+ concentration in blood serum. Because of their ability to complex metal anions- alkalides cryptands are used in ion chromatography and anionic polymerization.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:303307
Study programmeTitle: Chemistry
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2019-12-05 09:59:26