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master's thesis
Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama
2020. urn:nbn:hr:182:381732
Mršo, Tomislav
Josip Juraj Strossmayer University of Osijek
Department of Chemistry

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Mršo, T. (2020). Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama (Master's thesis). Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:381732

Mršo, Tomislav. "Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2020. https://urn.nsk.hr/urn:nbn:hr:182:381732

Mršo, Tomislav. "Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2020. https://urn.nsk.hr/urn:nbn:hr:182:381732

Mršo, T. (2020). 'Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama', Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 10 December 2024, https://urn.nsk.hr/urn:nbn:hr:182:381732

Mršo T. Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama [Master's thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2020 [cited 2024 December 10] Available at: https://urn.nsk.hr/urn:nbn:hr:182:381732

T. Mršo, "Sinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama", Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:182:381732

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Metadata
TitleSinteza i karakterizacija kompleksnih spojeva N,O-donornim makrocikličkim Schiffovim bazama
Title (english)Synthesis and characterization of N,o- donor macrocyclic Schiff base complexes
AuthorTomislav Mršo
MentorTomislav Balić (mentor)
Committee memberOlivera Galović (predsjednik povjerenstva)
Committee memberTomislav Balić (član povjerenstva)
Committee memberBrunislav Matasović (član povjerenstva)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
Osijek
Defense date and country2020-09-25, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Predmet istraživanja ovog diplomskog rada je sinteza i karakterizacija kompleksnih spojeva s N,O – donornim makrocikličkim Schiffovim bazama. Pripremljene su 4 makrocikličke Schiffove baze (L1, L2, L3, L4) koje su služile kao ligandi tj. kao N,O - donori, kao metalni kationi prijelaznih elemenata koristili su se srebrov nitrat \( \left ( AgNO_{3} \right ) \)i srebrov perklorat \( \left ( AgC1O_{4} \right )\). Priprava kompleksnih spojeva izvedena je uz odgovarajući ligand i metalni kation na temperaturi refluksa uz diklormetan i metanol kao otapalo. Od izvedenih sinteza metodom difuzije uspješno su izolirana i identificirana 3 spoja (\( AgL1C1O_{4} \), \( AgL2C1O_{4} \) i \( Ag_{2}\left ( L2_{2} \right )\left ( NO_{3} \right )_{2} \). Dobiveni spojevi su karakterizirani IR spektroskopijom (FTIR) koja ukazuju na koordinaciju imino skupine sa atomom srebra. Molekulske i kristalne strukture određene su rendgenskom difrakcijom.
Abstract (english)
The subject of this diploma thesis is the synthesis and characterization of N,O – donor macrocyclic Schiff base complexes. 4 macrocyclic Schiff bases (L1, L2, L3, L4) were prepared and used as ligands, ( N,O – donors), silver nitrate \( \left ( AgNO_{3} \right ) \) and silver perchlorate \( \left ( AgC1O_{4} \right )\) were used as a metal cations of transition elements. The preparation of complex compounds was performed with the appropriate ligand and metal cation at reflux temperature with dichloromethan and methanol as solvent. From performed syntheses by diffusion method, 3 compounds were successfully isolated and identified (\( AgL1C1O_{4} \), \( AgL2C1O_{4} \) and \( Ag_{2}\left ( L2_{2} \right )\left ( NO_{3} \right )_{2} \). The synthesis compounds were characterized by IR spectroscopy (FTIR) and results indicate coordination of the imino group with the silver atom. Molecular and crystal structure were determined by single-crystal X-ray diffraction.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:381732
Study programmeTitle: Graduate University Study of Chemistry; research direction
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2020-11-04 10:15:07