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master's thesis
Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva
2021. urn:nbn:hr:182:535109
Lastrić, Adrijana
Josip Juraj Strossmayer University of Osijek
Department of Chemistry
Department of General, Inorganic and Physical Chemistry and Methodology of Chemistry

Cite this document

Lastrić, A. (2021). Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva (Master's thesis). Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:535109

Lastrić, Adrijana. "Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2021. https://urn.nsk.hr/urn:nbn:hr:182:535109

Lastrić, Adrijana. "Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2021. https://urn.nsk.hr/urn:nbn:hr:182:535109

Lastrić, A. (2021). 'Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva', Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 15 March 2023, https://urn.nsk.hr/urn:nbn:hr:182:535109

Lastrić A. Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva [Master's thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2021 [cited 2023 March 15] Available at: https://urn.nsk.hr/urn:nbn:hr:182:535109

A. Lastrić, "Određivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva", Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:182:535109

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Metadata
TitleOdređivanje supramolekulskih sintona u kristalnim strukturama oksa-aza makrocikličkih spojeva
Title (english)Determination of supramolecular synthons in crystal structures of oxa-aza macrocyclic compounds
AuthorAdrijana Lastrić
MentorTomislav Balić (mentor)
Committee memberOlivera Galović (predsjednik povjerenstva)
Committee memberTomislav Balić (član povjerenstva)
Committee memberAna Amić (član povjerenstva)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
(Department of General, Inorganic and Physical Chemistry and Methodology of Chemistry)
Osijek
Defense date and country2021-09-23, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Inorganic Chemistry
Abstract
Markociklički spojevi najčešće su korišteni spojevi supramolekulske kemije. Primjenom koncepta supramolekulske kemije na čvrsto agregatno stanje govorimo o kristalnom inženjerstvu. Kristalno pakiranje povezano je s prirodom međumolekulskih interakcija. Klasična vodikova veza primjer je jake međumolekulske interakcije i ima značajnu ulogu u stvaranju supramolekulskih kristala. Snaga vodikovih veza ovisi o vrsti elektronegativnog atoma na koji je atom vodika pričvršćen i geometriji vodikovih veza. Supramolekulski sintoni su strukturne jedinice sastavljene od molekulskih i supramolekulskih elemenata, koje u kristalnoj strukturi čine mrežu motiva. Neki sintoni korisniji su od drugih sintona i kao takvi imaju puno veći utjecaj na pakiranje molekula u kristalnoj strukturi. Za jednostavno opisivanje sintona koristi se graf-set nomenklatura. Graf-set se prvo primjenjuje na motiv a zatim na mrežu. CSD baza podataka sadrži korisne informacije za ispitivanje sintona i međumolekulskih interakcija.
Abstract (english)
Macrocyclic compounds are the most used compounds of supramolecular chemistry. By applying the concept of supramolecular chemistry to a solid-state, we are talking about crystal engineering. The crystal packing is related to the nature of intermolecular interactions. The classical hydrogen bond is an example of a strong intermolecular interactions and plays a significant role in the formation of supramolecular crystals. The strength can vary between different systems and depend on the type of electronegative atom to which the hydrogen atom is attached and the geometry that hydrogen bond forms in the structure. Supramolecular synthons are structural units composed of molecular and supramolecular elements, which in the crystal structure form a network of motifs. Some synthons are more useful than other synthons and as such have a much greater impact on the packing of crystal structures. A graph-set nomenclature is used to simplify the description of synthon. Usually the graph-set is applied first to the motive and then to the network. The CSD database contains useful information for examining synthons and intermolecular interactions.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:535109
Study programmeTitle: Graduate University Study of Chemistry; research program; specializations in: Research program
Course: Research program
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2022-08-03 07:58:16