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master's thesis
Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom
2024. urn:nbn:hr:182:280977
Pritišanac, Ivan
Josip Juraj Strossmayer University of Osijek
Department of Chemistry
Department of Analytical, Organic and Applied Chemistry

Cite this document

Pritišanac, I. (2024). Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom (Master's thesis). Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:280977

Pritišanac, Ivan. "Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2024. https://urn.nsk.hr/urn:nbn:hr:182:280977

Pritišanac, Ivan. "Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2024. https://urn.nsk.hr/urn:nbn:hr:182:280977

Pritišanac, I. (2024). 'Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom', Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 28 November 2024, https://urn.nsk.hr/urn:nbn:hr:182:280977

Pritišanac I. Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom [Master's thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2024 [cited 2024 November 28] Available at: https://urn.nsk.hr/urn:nbn:hr:182:280977

I. Pritišanac, "Određivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom", Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:182:280977

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TitleOdređivanje anionskih tenzida u komercijalnim sustavima novim all-solid-state potenciometrijskim senzorom
Title (english)Determination of anionic surfactants in commercial systems using a new all-solid-state potentiometric sensor
AuthorIvan Pritišanac
MentorMateja Budetić (mentor)
Committee memberMirela Samardžić (predsjednik povjerenstva)
Committee memberMateja Budetić (član povjerenstva)
Committee memberMartina Šrajer Gajdošik (član povjerenstva)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
(Department of Analytical, Organic and Applied Chemistry)
Osijek
Defense date and country2024-09-16, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Analytic Chemistry
Abstract
U ovom radu koribten je novorazvijeni all-solid-state senzor sa vrstom membranom za određivanje anionskih tenzida u komercijalnim sustavima. Membrana norazvijenog senzora se sastoji od ionskog para DDA-TPB (dimetildioktadecilamonijev tetrafenil borat) koji je koribten kao senzorski materijal, te grafita i o-NPOE-a (2-nitrofenil oktil eter) kao plastifikatora. Metoda koribtena u istra~ivanju je potenciometrijska titracija. Ispitana su etiri razli ita titranta (cetilpiridinijev klorid, heksadeciltrimetilamonijev bromid, diizobutil-fenoksietoksi etil-dimetil benzil amonijev klorid i 1,3-didecil-2-metilimidazolijev klorid) koncentracije 4 × 10⁻³ mol L-1, pri emu je kao analit koribtena otopina natrijeva dodecil sulfata. Kao najpogodniji titrant izabran je cetilpiridinijev klorid zbog najve e to nosti i najve eg skoka potencijala u ekvivalentnoj to ki. Primjena novog all-solid-state potenciometrijskog senzora ispitana je određivanjem sadr~aja anionskih tenzida u tri komercijalna proizvoda, a metodom standardnog dodatka ispitana je to nost senzora. Rezultati su pokazali zadovoljavaju u preciznost i to nost prilikom određivanja sadr~aja anionskih tenzida u komercijalnim uzorcima pomo u novog all-solid-state potenciometrijskog senzora kao detektora zavrbne to ke titracije.
Abstract (english)
In this work, a newly developed all-solid-state sensor with a solid membrane was used for the determination of anionic surfactants in commercial systems. The membrane of the newly developed sensor consists of the ion pair DDA-TPB (dimethyldioctadecylammoniumtetraphenylborate), which was used as the sensor material, graphite and o-NPOE (2-nitrophenyl octyl ether) as plasticizer. The method used in the research is potentiometric titration. Four different titrants (cetylpyridinium chloride, hexadecyltrimethylammonium bromide, diisobutylphenoxyethoxy ethyl-dimethyl benzyl ammonium chloride and 1,3-didecyl-2-methylimidazolium chloride) with a concentration of 4 × 10⁻³ mol L-1 were tested, while the analyte was sodium dodecyl sulfate solution. Cetylpyridinium chloride was chosen as the most suitable titrant due to the highest accuracy and the highest potential jump at the equivalent point. The application of the new all-solid-state potentiometric sensor was tested by determining the content of anionic surfactants in three commercial products, and the accuracy of the sensor was tested using the standard addition method. The results showed satisfactory precision and accuracy when determining the content of anionic surfactants in commercial samples using a new all-solid-state potentiometric sensor as a titration endpoint detector.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:280977
Study programmeTitle: University Graduate Study of Chemistry; Research Program; specializations in: Research Program
Course: Research Program
Study programme type: university
Study level: graduate
Academic / professional title: sveučilišni/a magistar/magistra kemije (sveučilišni/a magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2024-10-03 11:45:48